With appropriate product upgrading, synthetic fuels produced from the DCL process can be directly used in the current motor engines. However, similar to other coal liquefaction processes, the DCL process has not been widely commercialized mainly because of economic uncertainty, high CO 2 emission, and high capital cost [1], [2].
The use of highcarbonbased feeds to produce alternative fuels and valueadded chemicals is discussed. Basic conversion chemistry, chemical structures of coal and lignin biomass are discussed, followed by process technologies for direct liquefaction, liquid quality, process control and modeling, advantages and limitations, and future trends.
To improve the performance of megaton direct coal liquefaction (DCL) technology that has been practiced in China since 2008 and to develop a better technology that can be operated at milder conditions with high efficiency, this work studies coal conversion (X C), products yield (Y i) and hydrogen consumption (R H) of SW coal (H/C = ) used in the megaton plant and NMH coal of a higher H/C ...
There remains an important need for economical coal and biomass to liquids conversion processes with reduced carbon dioxide emissions and efficient use of carbon resources. ... 1—CO 2 carbon capture and conversion to a biological material such as algae; 2—direct coal liquefaction (DCL); 3—indirect conversion of biomass and/or coal to ...
The liquefaction process of coal and biomass materials, which is known as "Coliquefaction", has not been developed in Malaysia. The yields and quality (especially H/C ratio) of the liquid products obtained from coal under less severe liquefaction conditions (at lower temperature and pressure) can be improved with coliquefaction of coal ...
Coal liquefaction is a process of converting coal into liquid hydrocarbons: liquid fuels and process is often known as "Coal to X" or "Carbon to X", where X can be many different hydrocarbonbased products. However, the most common process chain is "Coal to Liquid Fuels" (CTL).
Coal can also be liquefied directly into liquid fuels through direct coal liquefaction (DCL) processes at around 450500 °C under 1530 MPa H 2 in a suitable solvent with appropriate catalysts [ 2, 3, 4, 5, 6, 7, 8, 9 ].
The environmental footprint of coal liquefaction processes can usually be reduced by coprocessing coal and biomass and applying CO 2 capture and storage (CCS) technology but at the cost of higher ...
The separate characterization of biomass, coal, and their respective chars aimed at identifying the effect of sodium during different stages of combustion. ... Direct coal liquefaction (DCL) is a main pathway for converting lowrank coals into energy via thermochemical transformation [713], and DCL technology refers to conversion of solid ...
The use of highcarbonbased feeds to produce alternative fuels and valueadded chemicals is discussed. Basic conversion chemistry, chemical structures of coal and lignin biomass are discussed, followed by process technologies for direct liquefaction, liquid quality, process control and modeling, advantages and limitations, and future trends.
The decomposition process in coal liquefaction is consisting of pyrolysis, solvent extraction and liquefaction processes directly or indirectly [2] [3][4]. The pyrolysis reaction is a complex ...
CoaltoLiquids (CTL) is a technology based on the liquefaction of coal using three basic approaches; pyrolysis, direct coal liquefaction (DCL) and indirect coal liquefaction (ICL) [6] . Historical overview. CTL is an old technique, developed at the beginning of the 20 th century and has recently attracted attention once more.
The environmental footprint of coal liquefaction processes can usually be reduced by coprocessing coal and biomass and applying CO 2 capture and storage (CCS) technology but at the cost of higher ...
For the most highly developed processes, coal conversion can be as high as 90% on a mineral ash free basis, with a C 5+ distillate yield up to 75% and hydrogen consumption of 57% wt. When an external catalyst is used, it is typically some combination of cobalt, nickel, and molybdenum on a solid acid support such as silicaalumina [].In slurry hydrogenation processes, catalyst lifetime is ...
The environmental footprint of coal liquefaction processes can usually be reduced by coprocessing coal and biomass and applying CO 2 capture and storage (CCS) technology but at the cost of higher ...
Generally, Fig. 1 shows the distinct difference between the direct and indirect liquefaction processes. Importantly, DCL consists of many steps for the conversion of coal to PA (preasphaltenes) and AS (asphaltenes), and subsequently to gas, oil, and residue [60]. Download : Download highres image (180KB) Download : Download fullsize image ...
When considering the development of coal liquefaction process using syngas, in addition to the above typical processes, hydrothermal liquefaction process is a technology worthy of reference. Hydrothermal liquefaction [110], [111], [112] is an effective and emerging technology that can convert both coals and biomass containing high moisture ...
1Solidhydrocarbonfuelprocessingandtechnology103 4 Directliquefaction (DCL)processes andtechnology forcoalandbiomass conversion105 C. BurgessCliffordandC.
Headwaters direct coal liquefaction process. Source: Headwaters. Click to enlarge. Headwaters Inc and Axens are forming a strategic alliance to provide a singlesource solution for producing synthetic fuels by direct coal liquefaction (DCL) alone or in combination with refinery residues or biomass. The two companies will combine their technologies and...
Coal to liquid technology includes direct coal liquefaction (DCL), indirect coal liquefaction (ICL), coal to methanol to gasoline (CTMTG), and coal tar hydrogenation (CTH) (Xie, 2021; Zhang et al ...
Characterization of Oxygenated Species in Coal Liquefaction Products: An Overview. ... Z. R. Ismagilov. The relationship between the molecular composition of coal and the conversion of its organic matter during thermal dissolution. Carbon Letters 2022, 32 (4 ... (DCL) processes and technology for coal and biomass conversion. 2011 ...
Other thermochemical conversion technologies are under development for coprocessing biomass and fossil fuels. During the coliquefaction of coal with biomass, lower liquefaction temperature of coal and higher liquid products yield than those predicted by mathematic models are obtained as a result of the synergetic effect.
Coal can also be liquefied directly into liquid fuels through direct coal liquefaction (DCL) processes at around 450500 °C under 1530 MPa H 2 in a suitable solvent with appropriate catalysts [2,3,4,5,6,7,8,9]. In many processes, the solvent used can facilitate the heat and mass transfer during chemical reactions, and function as a ...
To meet future demand in motor fuels, coal will play a key role in areas with large coal resources and lacking crude oils. Axens' direct coal liquefaction (DCL) process is available to produce ...
Keywords: direct coal liquefaction (DCL); processes; influencing factors; coal pretreatment; catalysts; coliquefaction; biomass 1. Introduction Due to the rapid increase in demand for petroleum and its declining reserves, the concern over energy security has intensified the interest in coal liquefaction, especially for those countries which are
The results showed the price of coal had a more dominant effect on RSP than that of biomass. Different mix ratios and conversion rates led to RSP ranging from /bbl. LCA results indicated that GHG emissions ranged from kg CO2 eq to kg CO 2 eq/1000 MJ of liquid fuel at various biomass to coal mix ratios and ...
The conversion of coal to products soluble in tetrahydrofuran correlated strongly with the initial rate of gas uptake. The cyclohexane conversion of coal was also catalyzed. ... (DCL) processes and technology for coal and biomass conversion. 2011, 105154. ... A new process for catalytic liquefaction of coal using dispersed MoS2 catalyst ...
The Energy and Environmental Research Center (EERC), in partnership with the Department of Energy (DOE) and Accelergy Corporation, an advanced fuels developer with technologies exclusively licensed from ExxonMobil, undertook Subtask to design, build, and preliminarily operate a benchscale direct coal liquefaction (DCL) system capable of converting 45 pounds/hour of pulverized, dried ...
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