The present data reveal that coalderived distillates generated by the Hcoal process are highly carcinogenic to mouse skin. An extreme form of neurotoxicity associated with dermal exposure to one of the lighter, minimally carcinogenic, materials was noted.
This document contains the final results of an investigation to determine the suitability of the COED, HCOAL, SYNTHOIL, and SRC II syncrudes as petrochemical feedstocks. Based on the results of laboratory investigations, conversions of the liquid products to petrochemical feedstocks per ton of coal fed to each liquefaction process was % ...
The HCoal processes: A status report A catalytic process (HCoal) involving the direct hydrogenation of coal to produce hydrocarbon liquids is described. Benchscale and pilot plant development of the HCoal process is reported. Emphasis is placed on a proposed pilot plant which will be the largest coal liquefaction plant online in the, processing up to 600 tpd of coal.
Pulverized coal is mixed with recycle slurry oil to form a coaloil slurry. This slurry is passed through a heater into the lower part of the reactor. H is added, and the oil and H pass up through a bed of catalyst or activated Al/sub 2/O/sub 3/ at sufficient velocity to maintain an ebullated bed of catalyst or inert solids.
The HCoal Process The HCoal process liquifies coal to either boiler fuel or synthetic crude in the presence of an added particulate catalyst. To produce synthetic crude instead of boiler fuel, more hydrogen is added to the slurry and reactor residence times are increased. It was developed by Hydrocarbon Research, Inc. (HRI) and was selected ...
Synthoil, HCoal, and Exxon donor solvent processes. Final report Feb 77Aug 78}, author = {Parker, C L and Dykstra, D I}, abstractNote = {This volume is an environmental characterization of three selected coal liquefaction systems: Synthoil, HCoal, and Exxon Donor Solvent. It documents and evaluates existing environmentally significant data.
A process that has been used for the conversion of coal to liquid products is the HCoal Process disclosed in Pat. Nos. 3,519,555 and 3,540,995 which converts coal to gaseous and liquid products by hydrogenation in an ebullated catalyst bed reactor.
The Hcoal process of Hydrocarbon Research was developed in a 200 t/d plant in Catlettsburg (Kentucky). The main partners participating in this project were the DOE and Ashland Oil together with other energy com panies. Hydrogenation is conducted under relatively mild reaction condi tions of 455 and 210 bar with a cobalt/molybdenum catalyst.
Specifically, Dow is testing the liquids produced from four coal liquefaction processes (COED, SRC, Synthoil, and HCoal) in standard petrochemical processing experiments and is evaluating these results to select one process for further study, based on process design, quality of chemicals produced, and overall plant economics.
HCoal, a catalytic hydroliquefaction process developed by Hydrocarbon Research, Inc. for conversion of coal to highquality, clean liquids, has advanced to the stage of commercial evaluation with the construction in Catlettsburg, Kentucky of a 600 ton/day pilot plant which will produce up to 2,500 barrels per day of liquid product.
The interaction of coalderived liquids with precoat materials was studied using the product oil filtrate from the liquefaction of an Illinois No. 6 Coal in the HCoal process. A study was initiated to determine the effect of precipitation inducing solvents on the filtration of a product oil slurry produced from a Kentucky No. 9 Coal in the SRC ...
HCOAL PROCESS LLJ EnvironinHnial Piotaclion Agency Office of Rfisuatch and Development Washington, D. C. 20460 ... LIST OF TABLES No._ I^ 1 Inputs to HCoal Plant 10 2 Outputs from HCoal Plant 11 3 Description of Streams for HCoal Liquefaction Plant 14 4 Sulfur Balance HCoal Plant 40 5 Thermal Efficiency HCoal Plant 42 6 Example of ...
The most important process of this group is the HCoal process, developed by Hydrocarbon Research, Inc. (HRI) as an outgrowth of previous work on the hydrogenation of petroleum fractions. The development of this process was sponsored by ERDA/US DOE and a large group of oil companies (DOE, 2015b; Xinjua News, 2014). Very few DCL programs were ...
Mining coal. Coal miners use large machines to remove coal from the earth. Many coal deposits, called coal beds or seams, are near the earth's surface, but others are deep mining methods allow coal miners to easily reach most of the nation's coal reserves and to produce about three times more coal in one hour than in 1978.
This report presents the results of a technical and economic evaluation of the HCoal process and the coaltomethanol process for the production of liquid fuels from coal. Evaluations are based on capital cost estimates, in mid1982 dollars, for commercial size, selfcontained plants with a nominal liquid product capacity of 50,000 fuel oil ...
HCoal Syncrude product streams, prepared from Illinois No. 6, Wyodak, or West Kentucky No. 11 coal were obtained from the HCoal Process Development Unit (PDU) and analyzed for physical properties, elemental compositions, trace metal levels, and molecular composition. The trace metal levels are generally low in all except the heavy fuel oils.
HCoal Processes. In the HCoal process, pulverized coal is slurried with recycled oil and, along with hydrogen, fed into an ebullatedbed reactor, a feature that distinguishes this process from others. Reactor conditions are normally in the range of 825 to 875°F and 2,500 to 3,500 psig. The reactor contains a bed of catalytic particles ...
the USA at the same time: the Exxon Donor Solvent (EDS) process and the HCoal process. The distinguishing feature of the EDS process was a separate solvent hydrogenation step to carefully control the hydrogen donor characteristics of the solvent, and the most important feature of the HCoal process was its use of an ebullated bed reactor.
This report presents the results of a technical and economic evaluation of the HCoal process and the coaltomethanol process for the production of liquid fuels from coal. Evaluations are based on capital cost estimates, in mid1982 dollars, for commercial size, selfcontained plants with a nominal liquid product capacity of 50,000 fuel oil ...
The HCoal process was a starting basis for subsequent process development sponsored by the US DOE over about three decades time. A principal focus of this longterm project was RD of catalysts that were tolerant of, and would not be rapidly deactivated by, coalderived mineral matter in the reactor. Typical early catalysts showed rapid ...
• The Hcoal process differs from other processes in that the coaloil slurry comes in direct contact with a catalyst in the reactor. • Five major steps are involved In the H Coal process:
The HCoal process has been studied in demonstration units and on a pilot scale by HRl under sponsorship of DOE (1). The complete design of a pilot plant having a throughput of 600 ton/day of coal, has been performed by HRl Engineering. This plant fs being built at Catlettsburg, Ky. The process is shown in Figure I in schematic form.
Abstract. The book discusses the establishment of the Synthetic Fuels Corporation by the Energy Security Act and the barriers to commercialization of coal gasification, coal liquefaction, and oil shale technologies for synfuel production; reviews the equipment and processes for coal gasification and coal liquefaction; assesses the current status of the HCoal Process; illustrates the ...
The rerun HCoal atmospheric still bottoms (Hcoal gas oil) were used to evaluate the relative hydrogenation activity of three UOP commercial catalysts. The UOPDCB catalyst, which was found to have the highest hydrogenation activity, was employed in the HCoal gas oil hydrotreating process more » variable studies.
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